The filtrate, if shaken up with amylic
alcohol, gives it in either case a red color. A knowledge of this fact
is important, or it may be mistaken for magenta. The behavior of the
amylic alcohol, thus colored red, with hydrochloric acid and ammonia is
characteristic. If the red color is due to magenta, it is destroyed by
both these reagents, while hydrocholoric acid does not decolorize the
solutions of archil and cudbear, and ammonia turns their red color to a
purple violet. If the wine is examined according to the Falieres-Ritter
method in presence of magenta, ether, when shaken up with the wine,
previously rendered ammoniacal, remains colorless, while if archil
or cudbear is present the ether is colored red. Wartha has made a
convenient modification in the Falieres-Ritter method by adding ammonia
and ether to the concentrated wine while still warm. If the red color of
the wool is due to archil or cudbear, it is extracted by hydrochloric
acid, which is colored red. Ammonia turns the color to a purple violet.
Koenig mixed 50 c.c. wine with ammonia in slight excess, and places in
the mixture about one-half grm. clean white woolen yarn. The whole is
then boiled in a flask until all the alcohol and the excess of ammonia
are driven off.
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